You can assign XP to open or run programs based on your choice in the new AutoPlay tab in drive properties. But...
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there isn't an easy way to add or change your choices -- enter XP PowerToys.
- Download Microsoft's PowerToys for XP and install.
- Run TweakUI. Choose My Computer from the list.
- Click the + on AutoPlay, then select Handlers.
From here, you can add your own selections or edit existing selections at will. For example, you may want to run a CD player you purchased when you insert a music disk.
When finished, close TweakUI, right click on your drive, click on the AutoPlay tab and you will see your entry.