Here are some good resources:
https://www.oreilly.com/catalog/winsyspe/ (This is a book on System Policies.)
http://www.microsoft.com/windows2000/en/server/help/default.asp?url=/windows2000/en/server/help/poleditAD.htm?id=925 (Use the Windows 2000 version of Systems Policy editor to create the template.)
http://www.microsoft.com/office/ork/2003/seven/ch26/SecD02.htm (This has quite a bit that is only Office related, but does address the issue of using System Policies on Windows 2000 to do other things.)
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